Wondering if Entity Framework 5 supports unique constraints on entity properties? If so, how can I specify that a property should be unique?
No, it doesn't. There were plans in the past to include a unique constraint feature in EF 5.0:
http://blogs.msdn.com/b/efdesign/archive/2011/03/09/unique-constraints-in-the-entity-framework.aspx
But you can see that there is an update on top of the post:
Update: this feature has been postponed and will not be included in Entity Framework 5.
You can vote on the feature to raise possibly the priority it gets implemented with...
...because apparently it isn't even on the roadmap for EF 6.0 at the moment: