Here is my grid i what to give an explanation to the header "RED.BROJ" when on mouse over that header to show the expl. text.
<ListView.View>
<GridView>
<GridViewColumn Width="50"
Header="Реd.Број"
DisplayMemberBinding="{Binding Path=RedenBroj}">
</GridViewColumn>
You could do this:
<GridViewColumn Width="50"
DisplayMemberBinding="{Binding Path=RedenBroj}">
<GridViewColumn.Header>
<TextBlock Text="Ред.Број"
ToolTip="Your explanation" />
</GridViewColumn.Header>
</GridViewColumn>