Here is a demo query, notice it is very simple, Fetches only where base_price is 0, And still, it chooses the condition 3:
SELECT
CASE course_enrollment_settings.base_price
WHEN course_enrollment_settings.base_price = 0 THEN 1
WHEN course_enrollment_settings.base_price<101 THEN 2
WHEN course_enrollment_settings.base_price>100 AND
course_enrollment_settings.base_price<201 THEN 3
ELSE 6
END AS 'calc_base_price',
course_enrollment_settings.base_price
FROM
course_enrollment_settings
WHERE course_enrollment_settings.base_price = 0
base_price
is decimal(8,0)
When run this on my DB, I get:
3 0
3 0
3 0
3 0
3 0