I am reading 'Operation System Concepts With Java'. I am quite confused by the concept of blocking and synchronous, what are the differences between them?
Blocking may or may not be the same as synchronous, depending on the context. When we talk about method calls, then a synchronous call can also be said to be blocking (I'll get back to this in a bit), because the thread calling the method cannot proceed forward until the method returns. The antonym in this case would be asynchronous.
In lock terminology, a lock is said to be blocking if the thread waiting to acquire it is put in a suspended mode until the lock becomes available (or until a timeout elapses). The antonym in this case is a non-blocking lock, meaning that the thread returns immediately even if it cannot acquire the lock. This can be used to implement the so called spinning lock, where you keep polling the state of the lock while keeping the thread active.
Having said this, you can extrapolate the difference between the concepts: synchronous generally means an activity that must wait for a reply before the thread can move forward. Blocking refers to the fact that the thread is placed in a wait state (generally meaning it will not be scheduled for execution until some event occurs). From here you can conclude that a synchronous call may involve blocking behavior or may not, depending on the underlying implementation (i.e. it may also be spinning, meaning that you are simulating synchronous behavior with asynchronous calls).