Already understanding that AES is the encryption method of choice, should existing code that uses DES be re-written if the likely threat is on the level of script kiddies? (e.g. pkzip passwords can be cracked with free utilities by non-computer professionals, so is DES like that?) A quick google search seems to imply that even deprecated DES still requires a super computer and large quantity of time--or have times changed?
In particular, this CAPTCHA library uses DES to encrypt the challenge string which is sent to the user in viewstate.
DES is broken so far as storing sensitive data, and so I would certainly not use it in anything new, and would replace it in anything used for long term storage of any information of interest (data that someone would have a profit for national security interest in stealing).
At the moment a DES message can be broken by brute force in a couple of days (or less) using under $100,000 worth of custom hardware.
But there are some key factors in that:
The hardware is custom - the chips used to quickly brute a DES key are not the general purpose processor you'd find in a PC. That being said there is probably room today for using a cluster of Playstation 3s or current generation graphics cards with a GPGPU to crack a DES message in a reasonable amount of time, perhaps bringing down the cost to maybe $15,000.
The other factor is time - a DES message can be cracked in a day, but if your CAPTCHA library has a timestamp that specifies a 30 minute timeout for any given CAPTCHA response, it would still be effective (you could scale up your hardware, but then you're talking millions).
Overall I'd say that for non-long term storage, DES is still secure against "script kiddies".