I'm now going to learn ARM Assembly, to develop for my Windows Mobile 5 iPAQ, but I have some questions:
Main differences:
ARM is a RISC style architecture - instructions have a regular size (32-bit for standard ARM and 16-bits for Thumb mode, though Thumb has some instructions that chew up 2 instruction 'slots')
up through at least ARM v5 architecture (I'm not sure what v6 does), the interrupt model on ARM is vastly different than on Intel - instead of pushing registers onto the stack, the ARM swaps to a different set of registers which 'shadow' the normal set. The mode of the processor determines which register file is visible (and not all registers are necessarily shadowed). it's a pretty complex arrangement. Newer ARM Architectures (v7 anyway) have an interrupt model that's closer to Intel's where registers are pushed on to the stack when an interrupt occurs.
Arm instruction have some interesting features that aren't in Intel's:
On the other side, the ARM can't do much with memory directly except load from and store to it. Intel assembly can perform more operations directly on memory.
Note that the ARM architecture version doesn't correspond directly to the actual ARM processor versions - for example, if I remember right the ARM7 is a architecture v5 processor. Personally, I find this far more confusing than it should be.
The ARM Architecture references are freely downloadable from http://www.arm.com. I also suggest getting copies of Hitex's guides to various ARM microcontrollers for a good starting point.
There have been several Stackoverflow questions regarding pointers to getting started with ARM. Reviewing them will give you a lot of good places to start: