Similar questions have been asked before and they all reached the conclusion that AJAX will not become obsolete. But in what ways is ajax better than websockets?
With socket.io, it's easy to fall back to flash or long polling, so browser compatibility seems to be a non-issue.
Websockets are bidirectional. Where ajax would make an asynchronous request, websocket client would send a message to the server. The POST/GET parameters can be encoded in JSON.
So what is wrong with using 100% websockets? If every visitor maintains a persistent websocket connection to the server, would that be more wasteful than making a few ajax requests throughout the visit session?
I think it would be more wasteful. For every connected client you need some sort of object/function/code/whatever on the server paired up with that one client. A socket handler, or a file descriptor, or however your server is setup to handle the connections.
With AJAX you don't need a 1:1 mapping of server side resource to client. Your # of clients can scale less dependently than your server-side resources. Even node.js has its limitations to how many connections it can handle and keep open.
The other thing to consider is that certain AJAX responses can be cached too. As you scale up you can add an HTTP cache to help reduce the load from frequent AJAX requests.